Alloy selection for service in hydrogen, fluoride, hydrofluoric acid and fluorine
Module of
Alloy selection for service in hydrogen, fluoride, hydrofluoric acid and fluorine

Learn to evaluate material performance in HF and fluorine environments through corrosion analysis and alloy behavior insights in this self-paced technical module.

Steel Applications
Alloy selection for service in hydrogen, fluoride, hydrofluoric acid and fluorine
Steel Applications
Nickel Institute
Nickel Institute

Steel Applications

Alloy selection for service in hydrogen, fluoride, hydrofluoric acid and fluorine

Full Code

APP0416NI205

Module Type

E-learning

Description

None

What you will learn

• Understand the fundamental corrosion mechanisms governing metal performance in anhydrous HF, aqueous HF solutions, and fluorine—including protective fluoride film formation, velocity effects, hydrogen-related damage, and oxygen-induced attack.
• Explain the behavior of major alloy families (carbon steel, stainless steels, nickel alloys, copper-nickel alloys, and precious metals) and how composition, fabrication, and temperature–concentration conditions determine suitability.
• Differentiate key nickel-containing alloys and stainless steels used in HF and fluorine environments, recognizing limitations such as stress-corrosion cracking, weld-metal sensitivity, and oxygen-accelerated corrosion.
• Evaluate the effects of contaminants, moisture, flow velocity, and temperature on corrosion rates, protective film stability, and failure risks in HF and fluorine service.
• Identify appropriate materials of construction for specific HF- and fluorine-handling equipment, including piping, pumps, valves, storage vessels, vaporizers, plant utilities, and fluorine transfer systems.
• Interpret corrosion data and iso-corrosion charts provided for nickel alloys and stainless steels to establish safe operating conditions and select optimal alloys.

Module content
EN

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